Quantum chemical study on anionic polymerization mechanism of propylene oxide. Yunhan Wen, Lorenz. The reactions were proved to follow a series-parallel irreversible homogeneous mechanism under both catalyzed and uncatalyzed conditions. These metrics are regularly updated to reflect usage leading up to the last few days. Zentralbl. Wiesław Hreczuch, Arkadiusz Chruściel, Karolina Dąbrowska, Martino Di Serio, Sun Yongqiang. T. Biegler, Maria P. Ochoa, Logan Matthews, Jeff Ferrio, John Weston, Nima Nikbin. the Altmetric Attention Score and how the score is calculated. E-mail:  [email protected]. Hyg. 1981; 174:383–404. Please check your email for instructions on resetting your password. Identification and quantification of polyethylene glycol types in polyethylene glycol methyl ether and polyethylene glycol vinyl ether. Bhajendra N. Barman, Donald H. Champion, Stephen L. Sjoberg. and you may need to create a new Wiley Online Library account. Matthias Rupp, Wulf Ruback, Elias Klemm. This study of the water‐contamination reactions of ethylene oxide was conducted by Arthur D. Little, Inc. with funding from, and under the auspices of, the Ethylene Oxide Industry Council, part of the American Chemistry Council. Kinetic data on the hydration of ethylene oxide was obtained from both uncatalyzed and heterogeneously catalyzed reactions using a pressurized batch reactor. Polyethoxylation and polypropoxylation reactions: Kinetics, mass transfer and industrial reactor design. View the notice. This article is cited by Kinetics of Ethoxylation and Propoxylation of Ethylene Glycol Catalyzed by KOH, Dipartimento di Chimica, Università degli studi di Napoli “Federico II”, via Cinthia, 80126 Napoli, Italy. Significant experimental and technical contributions were also made by staff from Shell Chemicals' Westhollow Technology Center in Houston, Texas, and Union Carbide Corporation's Research Center in South Charleston, West Virginia. https://doi.org/10.1016/j.ces.2020.116189, https://doi.org/10.1016/j.cjche.2018.02.020, https://doi.org/10.1016/j.ces.2013.04.030, https://doi.org/10.1016/j.cep.2013.09.012, https://doi.org/10.1016/j.micromeso.2011.12.056, https://doi.org/10.1016/j.chroma.2009.08.024. Statistical Robustness Study for Kinetic Models. Elio Santacesaria,, Martino Di Serio, and. More efficient direct oxidation of ethylene by air was invented by Lefort in 1931 and in 1937 Union Carbide opened the first plant using this process. This article has been corrected. Please note: If you switch to a different device, you may be asked to login again with only your ACS ID. Conceptual Process Design and Economic Analysis of a Process Based on Liquid–Liquid Extraction for the Recovery of Glycols from Aqueous Streams. Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. American Institute of Chemical Engineers 120 Wall St., 23rd floor New York, NY 10005 1-800-AIChemE (1-800-242-4363) (203) 702-7660 www.aiche.org. Synthesis and Properties Evaluation of Nonionic-Anionic Surfactants Suitable for Enhanced Oil Recovery Using Sea Water. Continuous reactor network design for rigid polyol production. Process Intensification in Practice: Ethylene Glycol Case Study, Chemical Industry & Chemical Engineering Quarterly, 2011 International Symposium on Advanced Control of Industrial Processes (ADCONIP), View 3 excerpts, cites methods and background, By clicking accept or continuing to use the site, you agree to the terms outlined in our. Amberjet 4200/HCO3− was used as the heterogeneous catalyst, which was found to be the most effective among the four types of cross-linked styrene−divinylbenzene anion-exchange resins tested.

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